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The model-free models

Extending the list of models given in Mandel et al. (1995); Fushman et al. (1997); Orekhov et al. (1999a); Korzhnev et al. (2001); Zhuravleva et al. (2004), the models built into relax include

\begin{subequations}\begin{align} m0 &= \{\},\\ m1 &= \{S^2\},\\ m2 &= \{S^2, ... ...au_f, S^2_f, \tau_s, R_{ex}\},\\ m9 &= \{R_{ex}\}.\end{align}\end{subequations}
The parameter Rex is scaled quadratically with field strength in these models as it is assumed to be fast. In the set theory notation, the model-free model for the spin system i is represented by the symbol $\mathfrak{F}_i$. Through the addition of the local τm to each of these models, only the component of Brownian rotational diffusion experienced by the spin system is probed. These models, represented in set notation by the symbol $\mathfrak{T}_i$, are
\begin{subequations}\begin{align} tm0 &= \{\tau_m\},\\ tm1 &= \{\tau_m, S^2\},\... ..._f, \tau_s, R_{ex}\},\\ tm9 &= \{\tau_m, R_{ex}\}.\end{align}\end{subequations}


The relax user manual (PDF), created 2024-06-08.