This is the model for 2-site exchange for off-resonance R_{1ρ}-type data from Trott et al. (2003). It is selected by setting the model to `TAP03'. The equation for the exchange process is
R_{1ρ} = | R_{1}cos^{2}θ + R_{1ρ}'sin^{2}θ | |
+ , | (11.78) |
in which, in addition to those parameters defined above for the `TP02' model,
The equation is accurate when populations are less skewed than the `TP02' model ( p_{A} p_{B}). Note that this model, as with the `TP02' model, has been superseded by the `MP05' model in the next section. The reference for this equation is:
More information about the TAP03 model is available from:
The relax user manual (PDF), created 2024-06-08.